螺旋聚苯乙炔膜的制备及其气体透过性能
贾宏葛1,21,2,
史永强11,3,
伦英慧11,4,
马立群1,21,5,
李发家11,6,
张明宇11,7
(1.齐齐哈尔大学 1. 材料科学与工程学院;2. 黑龙江省高校复合改性材料重点实验室，黑龙江 齐齐哈尔 161006;3.2. 黑龙江省高校复合改性材料重点实验室，黑龙江 齐齐哈尔 161007;4.2. 黑龙江省高校复合改性材料重点实验室，黑龙江 齐齐哈尔 161008;5.2. 黑龙江省高校复合改性材料重点实验室，黑龙江 齐齐哈尔 161009;6.2. 黑龙江省高校复合改性材料重点实验室，黑龙江 齐齐哈尔 161010;7.2. 黑龙江省高校复合改性材料重点实验室，黑龙江 齐齐哈尔 161011)
Preparation and Gas Permeation of Helical Polyphenylacetylene Membrane
JIA Hong-ge11,2,
2,SHI Yong-qiang11,3,
LUN Ying-hui11,4,
MA Li-qun1,21,5,
LI Fa-jia11,6,
ZHANG Ming-yu11,7
(1. College of Materials Science and Engineering;2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161006, Heilongjiang , China;3.2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161007, Heilongjiang , China;4.2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161008, Heilongjiang , China;5.2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161009, Heilongjiang , China;6.2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161010, Heilongjiang , China;7.2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161011, Heilongjiang , China)
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中文摘要: 利用非手性((nbd)Rh+［η6-(C6H5)B-(C6H5)3］)为催化剂，将3种手性苯乙炔单体与非手性苯乙炔单体按照不同的比例进行共聚，得到了高分子量的可溶苯乙炔共聚物。将得到共聚物利用溶剂挥发法进行制膜，然后采用圆二色光谱仪(CD)对共聚物的二级结构进行测试。结果表明：该膜对CO2有优先透过性能，共聚物主链上形成单手性螺旋结构。
Abstract:Three chiral polyphenylacetylene monomers and an achiral polyphenylacetylene monomer were copolymerized in different proportions using the achiral catalytic system ((nbd)Rh+［η6-(C6H5)B-(C6H5)3］) to give soluble high molecular weight copolymer of phenylacetylenes. The obtained copolymers were made into membranes by solvent evaporation method, and circular dichroism(CD) was used to test the secondary structure of the copolymers. Results showed that the membrane had priority permeability on CO2. The copolymers formed one-handed helical structure in the main chains.
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基金项目:国家自然科学基金(U1162123, 51103076)；教育部留学回国人员科研启动基金项目［2012］1707；黑龙江省自然科学基金项目(LC2011C12)(ZD201101)；黑龙江省教育厅科研项目(1251H012)(1253-NCET24)；黑龙江省研究生创新科研项目(YJSCX2012-391HLJ)
| Author Name | Affiliation | E-mail |
| JIA Hong-ge1 | 1. College of Materials Science and Engineering
2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161006, Heilongjiang , China | jiahongge11@hotmail.com |
| 2,SHI Yong-qiang1 | 1. College of Materials Science and Engineering
2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161007, Heilongjiang , China | |
| LUN Ying-hui1 | 1. College of Materials Science and Engineering
2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161008, Heilongjiang , China | |
| MA Li-qun1,2 | 1. College of Materials Science and Engineering
2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161009, Heilongjiang , China | maliqun6166@163.com |
| LI Fa-jia1 | 1. College of Materials Science and Engineering
2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161010, Heilongjiang , China | |
| ZHANG Ming-yu1 | 1. College of Materials Science and Engineering
2. Key Laboratory of Composite Modified Materials of College of Heilongjiang Province, Qiqihar University, Qiqihar 161011, Heilongjiang , China | |
引用本文：
贾宏葛1,2,史永强1,伦英慧1,马立群1,2,李发家1,张明宇1.螺旋聚苯乙炔膜的制备及其气体透过性能[J].功能高分子学报,2014,27(2):.
JIA Hong-ge1,2,SHI Yong-qiang1,LUN Ying-hui1,MA Li-qun1,2,LI Fa-jia1,ZHANG Ming-yu1.Preparation and Gas Permeation of Helical Polyphenylacetylene Membrane[J].Journal of Functional Polymers,2014,27(2):.
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