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DOI:
功能高分子学报:2013,26(2):-
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阿魏酸分子印迹复合膜的制备及性能
(1.西南交通大学生命科学与工程学院,成都 610031;2.西南交通大学生命科学与工程学院,成都 610032;3.西南交通大学生命科学与工程学院,成都 610033;4.西南交通大学生命科学与工程学院,成都 610034)
Preparation and Properties of Ferulic Acid Molecularly Imprinted Composite Membrane
(1.School of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China;2.School of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610032, China;3.School of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610033, China;4.School of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610034, China)
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中文摘要: 以聚偏氟乙烯微孔滤膜为支撑膜、阿魏酸为模板分子、α-甲基丙烯酸为功能单体、乙二醇二甲基丙烯酸酯为交联剂,采用紫外光引发原位聚合法制备阿魏酸分子印迹复合膜,并将其用于阿魏酸的分离提取。使用扫描电镜和红外光谱分析对印迹复合膜的形态和结构进行了表征;通过X射线衍射分析和拉伸测试等技术研究了印迹复合膜的晶体结构和力学性能;采用静态吸附法和平板超滤膜分离器考察了印迹复合膜的结合性能与渗透选择性能。结果表明:印迹复合膜对阿魏酸的结合容量高于对结构类似的肉桂酸,当吸附浓度为0.1 mmol/L时结合选择因子达到1.9。在渗透40 min时,印迹复合膜对阿魏酸渗透量为5.16 μmol/cm2,与肉桂酸相比,渗透选择性因子为1.74,渗透性能优于非印迹复合膜。
Abstract:Ferulic acid molecularly imprinted composite membrane(MIM) was prepared via in situ polymerization by UV-irradiation using microfiltration polyvinylidene fluoride (PVDF) membrane as the supported membrane, ferulic acid as template, metnacrylic acid(MAA) as functional monomer and ethylene-glycol dimethyacrylate(EGDMA) as cross-linking agent. MIM was used to extract the ferulic acid. The morphology and structure of the composite membrane were characterized by scanning electron microscopy and infrared spectroscopy. The crystal structure and mechanical properties of the composite membrane were researched by X-ray diffraction and tensile techniques. The binding ability and penetration choosing performance of the composite membrane were researched by static adsorptive method and flat ultrafiltration membrane separator. Results showed that ferulic acid molecularly imprinted composite membrane exhibited excellent combining for the ferulic acid with the combined selective factor 1.9 at the concentration of 0.1 mmol/L. When the membrane permeated for 40 min, penetration trough quantity of imprinted compo-site membrane was 5.16 μmol/cm2 for ferulic acid. Compared with cinnamic acid with the penetration selective factor 1.74, penetrated performance of molecularly imprinted composite membrane was better than the non-imprinted composite membrane.
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基金项目:中央高校基本科研业务费专项资金项目(SWJTU11CX112)
引用本文:
王娇,王枢,陈洪岩,王韬.阿魏酸分子印迹复合膜的制备及性能[J].功能高分子学报,2013,26(2):.
WANG Jiao,WANG Shu,CHEN Hong-yan,WANG Tao.Preparation and Properties of Ferulic Acid Molecularly Imprinted Composite Membrane[J].Journal of Functional Polymers,2013,26(2):.