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功能高分子学报:2013,26(2):-

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锆炔杂化树脂的制备及性能

张跃峰¹, 高晓梅², 周权³, 倪礼忠⁴

(1.华东理工大学材料科学与工程学院，特种功能高分子材料及相关技术教育部重点实验室，上海 200237;2.华东理工大学材料科学与工程学院，特种功能高分子材料及相关技术教育部重点实验室，上海 200238;3.华东理工大学材料科学与工程学院，特种功能高分子材料及相关技术教育部重点实验室，上海 200239;4.华东理工大学材料科学与工程学院，特种功能高分子材料及相关技术教育部重点实验室，上海 200240)

Synthesis and Properties of Zirconium-Acetylene Hybrid Resin

ZHANG Yue-feng¹, GAO Xiao-mei², ZHOU Quan³, NI Li-zhong⁴

(1.Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China;2.Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200238, China;3.Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200239, China;4.Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200240, China)

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中文摘要: 以四氯化锆、三氯乙烯及苯乙炔为原料，通过有机锂法合成锆炔杂化树脂（PZA），通过FT-IR、1H-NMR表征了其结构，利用FT-IR、DSC及TGA研究了PZA树脂的固化反应及耐热性能；采用XRD研究了PZA树脂固化物的烧结性能。结果表明：PZA树脂可以发生固化交联反应；其固化物具有一定的耐热性能，在氮气气氛中，失重10%的温度（Td10）达到500 °C，1 000 °C下的质量保留率达到80%；在空气气氛中，1 000 °C下烧结可形成四方氧化锆陶瓷。

中文关键词: 锆炔杂化树脂四氯化锆耐热性能残炭率

Abstract:A new kind of zirconium-acetylene hybrid resin was synthesized from trichloroethylene, phenylacetylene and zirconium tetrachloride using organolithium method. The structures of resin were characterized by FT-IR and 1H-NMR. Thermal curing process was monitored by DSC and FT-IR. Thermal and oxidative properties were evaluated by TGA analysis. Results showed the PZA resin can cure. The cured PZA resins had good thermal stability, the temperature of 10% mass loss (Td10) under nitrogen was up to 500 °C and the residual at 1 000 °C was 80%. α-ZrO2-containing ceramic was obtained after sintering at 1 000 °C.

keywords: zirconium-acetylene hybrid resin zirconium tetrachloride heat resistance residual char yield

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基金项目:国家自然科学基金（51073053）资助项目

Author Name	Affiliation	E-mail
ZHANG Yue-feng	Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China	ZHFeng929@163.com
GAO Xiao-mei	Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200238, China
ZHOU Quan	Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200239, China
NI Li-zhong	Key Laboratory of Specially Functional Polymeric Materials and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200240, China	lzhni@ecust.edu.cn

引用本文：
张跃峰,高晓梅,周权,倪礼忠.锆炔杂化树脂的制备及性能[J].功能高分子学报,2013,26(2):.
ZHANG Yue-feng,GAO Xiao-mei,ZHOU Quan,NI Li-zhong.Synthesis and Properties of Zirconium-Acetylene Hybrid Resin[J].Journal of Functional Polymers,2013,26(2):.

作者	单位	E-mail
张跃峰	华东理工大学材料科学与工程学院，特种功能高分子材料及相关技术教育部重点实验室，上海 200237	ZHFeng929@163.com
高晓梅	华东理工大学材料科学与工程学院，特种功能高分子材料及相关技术教育部重点实验室，上海 200238
周权	华东理工大学材料科学与工程学院，特种功能高分子材料及相关技术教育部重点实验室，上海 200239
倪礼忠	华东理工大学材料科学与工程学院，特种功能高分子材料及相关技术教育部重点实验室，上海 200240	lzhni@ecust.edu.cn

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