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中文摘要: 以丙烯酸(AA)、丙烯酰胺(AM)为单体,采用水溶液聚合法制备了低黏度聚(丙烯酸 丙烯酰胺)P(AA-co-AM)树脂。使用旋转黏度计和热重分析仪等测试了树脂的性质,并以该树脂为连接料,制备了新型水性氧化铟锡(ITO)蚀刻油墨。探讨了该油墨的保水性、pH变化和蚀刻图像解析度等。结果表明:通过优化合成工艺可制备分子量适宜的P(AA co AM)树脂,它在150 °C以下无分解现象;油墨在使用3 h后失水率仅为3.68%~5.34%,存放60 d后pH基本无变化,且丝网印刷效果明显好于市售油墨。
中文关键词: 氧化铟锡 聚(丙烯酸 丙烯酰胺) 连接料 蚀刻油墨
Abstract:The low viscosity poly(acrylic acid acrylamide) (P(AA-co-AM)) resin was synthesized by solution polymerization using acrylicacid and acrylamide as the monomers. The properties of the resin were characterized by rotational viscometer and thermogravimetric analyser. A new type of indium tin oxide (ITO) etching ink was prepared using P(AA-co-AM) resin as connection material. The water retention property, pH change and etched image resolution of the ink were evaluated. Results showed that the suitable resin can be prepared by optimizing the synthesis process. The so prepared resin didn't decompose beneath 150 °C. The water loss rate of the ink was range 3.68% and 5.34% after exposing to air for 3 h. The image resolution used this ink was better than the commercially available ink after storing 60 d. Moreover, the etching capability did not decline and pH value almost did not change.
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基金项目:基金项目:国家自然科学基金(21105030);广东省科技计划项目(2009B011000041,2009B090600079);华南农业大学211项目
(2009B010100001);广东省高等学校大学生创新实验项目(1056411138)
作者 | 单位 | |
钟英立 | 华南农业大学理学院,广州 510642 | zhongyingli@163.com |
杨鑫 | 华南农业大学理学院,广州 510643 | |
孙金媛 | 华南农业大学理学院,广州 510643 | |
陈建忠 | 华南农业大学理学院,广州 510644 | |
刘英菊 | 华南农业大学理学院,广州 510645 | |
杨卓鸿 | 华南农业大学理学院,广州 510646 | yangzhuohong@yahoo.com.cn |
引用本文:
钟英立,杨鑫,孙金媛,陈建忠,刘英菊,杨卓鸿.基于丙烯酸-丙烯酰胺共聚物的氧化铟锡蚀刻油墨的制备与性能[J].功能高分子学报,2012,25(2):.
ZHONG Ying li,YANG Xin,SUN Jin yuan,CHEN Jian zhong,LIU Ying ju,YANG Zhuo hong.Preparation and Properties of Indium Tin Oxide Etching Ink Based on Acrylic Acid Acrylamide Copolymer[J].Journal of Functional Polymers,2012,25(2):.
钟英立,杨鑫,孙金媛,陈建忠,刘英菊,杨卓鸿.基于丙烯酸-丙烯酰胺共聚物的氧化铟锡蚀刻油墨的制备与性能[J].功能高分子学报,2012,25(2):.
ZHONG Ying li,YANG Xin,SUN Jin yuan,CHEN Jian zhong,LIU Ying ju,YANG Zhuo hong.Preparation and Properties of Indium Tin Oxide Etching Ink Based on Acrylic Acid Acrylamide Copolymer[J].Journal of Functional Polymers,2012,25(2):.