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功能高分子学报:2010,23(4):345-350

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线型聚(苯乙烯-乙烯)嵌段共聚物氯甲基化交联特性

朱传涛^1,2, 罗云杰³, 陈飞⁴, 雷引林⁵

(1.浙江大学宁波理工学院，浙江宁波 315100;2.浙江大学化学工程与生物工程学系，杭州 310027;3.浙江大学宁波理工学院，浙江宁波 315100;4.浙江大学宁波理工学院，浙江宁波 315101;5.浙江大学宁波理工学院，浙江宁波 315102)

Cross Linking Properties in Chloromethylating Linear Polystyrene-b-Polyethylene

ZHU Chuan-tao^1,2, LUO Yun-jie³, CHEN Fei⁴, LEI Yin-lin⁵

(1.Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, Zhejiang, China;2.Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;3.Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;4.Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310028, China;5.Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310029, China)

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本文已被：浏览 1771次下载 1819次
投稿时间：2010-08-26

中文摘要: 线型聚(苯乙烯-乙烯)(PSE)嵌段共聚物在氯甲基化过程中，容易发生交联反应。为了表征交联反应的程度，先采用间接氯甲基化方法，在均相反应体系中实现了PSE的氯甲基化，然后通过傅里叶红外光谱(FT-IR)、氢核磁共振(1H-NMR)、差示扫描量热仪(DSC)和热失重分析仪(TGA)，对氯甲基化产物进行了分析表征。结果表明：氯甲基化产物用溶剂抽提称重与氢核磁谱图计算相结合的方法，可以准确地测定其交联程度；氯甲基化产物在220 ℃左右发生降解；交联反应会使产物的玻璃化温度升高，但会导致氯甲基基团更容易发生热分解。

中文关键词: 聚(苯乙烯-乙烯) 氯甲基化交联

Abstract:The cross linking reaction takes place spontaneously when chloromethylating linear polystyrene-b-polyethylene(PSE). An indirect chloromethylation of PSE was carried out in a homogeneous system. After that, FT-IR, 1H-NMR, TGA and DSC analysis were used to characterize the chloromethylated product. The results showed that the cross linking degree in chloromethylating PSE could be measured by solvent extraction combined with 1H-NMR spectroscopy. The chloromethylated product decomposed at 220 ℃. And the cross linking reaction led to the increase of the glass transition temperature of chlorome thylated product，but the thermal decomposition of the chloromethyl groups occured more easily.

keywords: polystyrene-b-polyethylene chloromethylation cross linking

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基金项目:宁波市国际合作项目资助(2009D10015)

作者	单位	E-mail
朱传涛	1.浙江大学宁波理工学院，浙江宁波 315100；2.浙江大学化学工程与生物工程学系，杭州 310027	nitzhuct@163.com
罗云杰	浙江大学宁波理工学院，浙江宁波 315100
陈飞	浙江大学宁波理工学院，浙江宁波 315101
雷引林	浙江大学宁波理工学院，浙江宁波 315102	leiyl@nit.net.cn

引用本文：
朱传涛,罗云杰,陈飞,雷引林.线型聚(苯乙烯-乙烯)嵌段共聚物氯甲基化交联特性[J].功能高分子学报,2010,23(4):345-350.
ZHU Chuan-tao,LUO Yun-jie,CHEN Fei,LEI Yin-lin.Cross Linking Properties in Chloromethylating Linear Polystyrene-b-Polyethylene[J].Journal of Functional Polymers,2010,23(4):345-350.

Author Name	Affiliation	E-mail
ZHU Chuan-tao	1.Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, Zhejiang, China； 2.Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China	nitzhuct@163.com
LUO Yun-jie	Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
CHEN Fei	Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310028, China
LEI Yin-lin	Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310029, China	leiyl@nit.net.cn

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