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投稿时间：2009-09-30
投稿时间：2009-09-30
中文摘要: 以工业生产废弃的稻壳灰为原料，采用化学沉淀法制备了大孔径多孔稻壳基白炭黑，并在多孔白炭黑(RHSi)分散体系中，采用原位聚合法制备了聚苯胺(PAn) 稻壳基白炭黑复合物。采用热重分析、傅里叶红外光谱、透射电镜、低温氮吸附法和循环伏安法研究了复合物的结构及电化学性能。结果表明：聚苯胺-稻壳基白炭黑复合物具有多孔聚集体结构。当mPAn/mRHSi=0.434时，复合物的比表面积为42.1 m2/g，最可几孔径约为22 nm，适宜负载生物大分子，且在酸性及中性溶液中具有良好的电化学可逆性。
Abstract:Large-pore silica white was prepared from industrial waste rice husk ash by chemical precipitation, and polyaniline-rice hull silica white composites were synthesized in the dispersion system of porous silica white by in-situ polymerization. The structure and electrochemical properties of composites were characterized by TGA, FT-IR, TEM, nitrogen adsorption and cyclic voltammetry. Results show that the morphology of composite is porous congeries. The composite (mPAn/mRHSi=0.434) exhibits specific area of 42.1 m2/g, and the most probable pore diameter of 22 nm. Its film electrode possesses good redox reversibility in acidic and neutral aqueous media.
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基金项目:食品科学与技术国家重点实验室基金(SKLF TS 200809);国家科技支撑计划（2006BAD05A10）
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引用本文：
李晓瑄,周蕴宇,陈正行.多孔聚苯胺-q稻壳基白炭黑复合物的制备及循环伏安特性[J].功能高分子学报,2009,(4):337-342.
.Preparation and Cyclic Voltammetry Properties of Porous Polyaniline-Rice Hull Silica White Composite[J].Journal of Functional Polymers,2009,(4):337-342.
李晓瑄,周蕴宇,陈正行.多孔聚苯胺-q稻壳基白炭黑复合物的制备及循环伏安特性[J].功能高分子学报,2009,(4):337-342.
.Preparation and Cyclic Voltammetry Properties of Porous Polyaniline-Rice Hull Silica White Composite[J].Journal of Functional Polymers,2009,(4):337-342.
