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DOI:10.14133/j.cnki.1008-9357.2017.04.001

功能高分子学报:2017,30(4):367-421

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烯烃阴离子聚合发展60年的现状与释疑的努力

郑安呐, 管涌, 危大福, 许祥, 陈波, 苏凌

(华东理工大学材料科学与工程学院, 上海市先进聚合物材料重点实验室, 超细材料制备与应用教育部重点实验室, 上海 200237)

Current Situation and Breakthrough Efforts of the Anionic Polymerization of Olefins after the Development for 60 Years

ZHENG An-na, GUAN Yong, WEI Da-fu, XU Xiang, CHEN Bo, SU Ling

(School of Materials Science and Engineering, Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China)

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本文已被：浏览 756次下载 845次
投稿时间：2017-05-04

中文摘要: 简述了依据阴离子聚合基本理论实施的反应挤出聚合，表述了其在工业应用领域的价值以及对阴离子聚合理论的贡献。回顾了烯烃阴离子聚合发展60年的历程，特别是近10年国内外烯烃阴离子活性聚合领域绝大部分的研究。在此基础上，列举了迄今为止烯烃阴离子聚合领域遗留的5大悬疑与2大发展瓶颈，引用本研究团队近20年来的研究，分别就阴离子聚合的释疑与突破进行了阐述。

中文关键词: 阴离子聚合烯烃现状释疑瓶颈

Abstract:The reactive extrusion for the polymerization of olefins based on the classic theory of anionic polymerization was briefly introduced. Its application value in the industrial fields and theoretical contribution to the anionic polymerization were mainly expressed. Then, the development of olefin anionic polymerization in 60 years, especially, most of the studies in this field over the past decade, were reviewed. Based on this, the 5 pieces of suspense and 2 major bottlenecks of the development remained in the anionic polymerization of olefins were pointed out. Through citing the researches of our team in recent 20 years, the interpretation of the suspense and the breakthrough in the bottlenecks were discoursed.

keywords: anionic polymerization olefin current situation interpretation of the suspense bottlenecks

文章编号： 中图分类号：TQ316.32 文献标志码：

基金项目:国家自然科学基金（29974008、50390091、50933002、51373052、51573043）

作者	单位	E-mail
郑安呐	华东理工大学材料科学与工程学院, 上海市先进聚合物材料重点实验室, 超细材料制备与应用教育部重点实验室, 上海 200237	zan@ecust.edu.cn
管涌	华东理工大学材料科学与工程学院, 上海市先进聚合物材料重点实验室, 超细材料制备与应用教育部重点实验室, 上海 200237	yguan@ecust.edu.cn
危大福	华东理工大学材料科学与工程学院, 上海市先进聚合物材料重点实验室, 超细材料制备与应用教育部重点实验室, 上海 200237
许祥	华东理工大学材料科学与工程学院, 上海市先进聚合物材料重点实验室, 超细材料制备与应用教育部重点实验室, 上海 200237
陈波	华东理工大学材料科学与工程学院, 上海市先进聚合物材料重点实验室, 超细材料制备与应用教育部重点实验室, 上海 200237
苏凌	华东理工大学材料科学与工程学院, 上海市先进聚合物材料重点实验室, 超细材料制备与应用教育部重点实验室, 上海 200237

Author Name	Affiliation	E-mail
ZHENG An-na	School of Materials Science and Engineering, Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China	zan@ecust.edu.cn
GUAN Yong	School of Materials Science and Engineering, Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China	yguan@ecust.edu.cn
WEI Da-fu	School of Materials Science and Engineering, Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China
XU Xiang	School of Materials Science and Engineering, Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China
CHEN Bo	School of Materials Science and Engineering, Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China
SU Ling	School of Materials Science and Engineering, Shanghai Key Laboratory of Advanced Polymeric Materials, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China

引用本文：
郑安呐,管涌,危大福,许祥,陈波,苏凌.烯烃阴离子聚合发展60年的现状与释疑的努力[J].功能高分子学报,2017,30(4):367-421.
ZHENG An-na,GUAN Yong,WEI Da-fu,XU Xiang,CHEN Bo,SU Ling.Current Situation and Breakthrough Efforts of the Anionic Polymerization of Olefins after the Development for 60 Years[J].Journal of Functional Polymers,2017,30(4):367-421.

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